Synthesis of a rotaxane CuI Triazolide under aqueous conditions
We describe the serendipitous isolation of a stable, neutral, monomeric mechanically interlocked CuI triazolide under aqueous conditions. This "trapped" intermediate of the CuAAC catalytic cycle is sterically protected from reprotonation by the rotaxane architecture, which renders the CuI-...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
2013-08-23.
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| Subjects: | |
| Online Access: | Get fulltext |