Synthesis of a rotaxane CuI Triazolide under aqueous conditions
We describe the serendipitous isolation of a stable, neutral, monomeric mechanically interlocked CuI triazolide under aqueous conditions. This "trapped" intermediate of the CuAAC catalytic cycle is sterically protected from reprotonation by the rotaxane architecture, which renders the CuI-...
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
2013-08-23.
|
Subjects: | |
Online Access: | Get fulltext |