A new polyborate anion, [B7O9(OH)6]3?: Self assembly, XRD and thermal properties of s-fac-[Co(dien)2][B7O9(OH)6]·9H2O
The title compound, s-fac-[Co(dien)2][B7O9(OH)6]·9H2O (1) (dien = HN(CH2CH2NH2)2), has been prepared as a crystalline solid in moderate yield (35%) from the reaction of B(OH)3 with [Co(dien)2][OH]3 in aqueous solution (10:1 ratio). The structure contains a novel polyborate anion [B7O9(OH)6]3 ? which...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
2015-09.
|
| Subjects: | |
| Online Access: | Get fulltext |