Phosphine complexes of aluminium(iii) halides - preparation and structural and spectroscopic systematics
Six-coordinate pseudo-octahedral complexes trans-[AlX2(L-L)2][AlX4] (X = Cl, Br or I; L-L = o-C6H4(PMe2)2, Me2P(CH2)2PMe2) are produced from reaction of AlX3 with the diphosphine in CH2Cl2 (X = Cl) or toluene (X = Br or I) solution. Four-coordinate dimers [Cl3Al(?-L?-L?)AlCl3] (L?-L? = Me2P(CH2)2PMe...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
2014-10-21.
|
| Subjects: | |
| Online Access: | Get fulltext |