Supramolecular Complexes Formed by the Self-assembly of Hydrophobic Bis(Zn2+-cyclen) Complexes, Copper, and Di- or Triimide Units for the Hydrolysis of Phosphate Mono- and Diesters in Two-Phase Solvent Systems (Cyclen=1,4,7,10-Tetraazacyclododecane)

Supramolecular Complexes Formed by the Self-assembly of Hydrophobic Bis(Zn2+-cyclen) Complexes, Copper, and Di- or Triimide Units for the Hydrolysis of Phosphate Mono- and Diesters in Two-Phase Solvent Systems (Cyclen=1,4,7,10-Tetraazacyclododecane)

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We previously reported on supramolecular complexes 4 and 5, formed by the 4:4:4 or 2:2:2 assembly of a dimeric zinc(II) complex (Zn2L1) having 2,2'-bipyridyl linker, dianion of cyanuric acid (CA) or 5,5-diethylbarbituric acid (Bar), and copper(II) ion (Cu2+) in an aqueous solution. The supermol...

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Bibliographic Details
Main Authors: Aoki, S (Author), Hisamatsu, Y (Author), Miyauchi, M (Author), Miyazawa, Y (Author), Yoneda, K (Author), Zulkefeli, M (Author)
Format: Article
Language:English
Published: 2016
Subjects:
AQUEOUS-SOLUTION
CHARGE-TRANSFER
ENZYME MIMICS
ESTER HYDROLYSIS
hydrolysis
MODEL
MOLECULAR RECOGNITION
phosphatase
PURPLE ACID-PHOSPHATASE
SELECTIVE RECOGNITION
self-assembly
supramolecular catalyst
two-phase solvent system
ZINC(II) COMPLEX
ZN2+ COMPLEXES
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