A novel and efficient synthesis of phenanthrene derivatives via palladium/norbornadiene-catalyzed domino one-pot reaction

Herein we report a novel palladium-catalyzed reaction that results in phenanthrene derivatives using aryl iodides, ortho-bromobenzoyl chlorides and norbornadiene in one pot. This dramatic transformation undergoes ortho-C–H activation, decarbonylation and subsequent a retro-Diels–Alder process. Pleas...

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Bibliographic Details
Main Authors: Yue Zhong, Wen-Yu Wu, Shao-Peng Yu, Tian-Yuan Fan, Hai-Tao Yu, Nian-Guang Li, Zhi-Hao Shi, Yu-Ping Tang, Jin-Ao Duan
Format: Article
Language:English
Published: Beilstein-Institut 2019-01-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.15.26